METHYL BENZOATE is an ester. P264 - P270 - P301 + P312 - P501. Qurum, Sultanate of Oman For information, call: 201-796-7100 Esters react with acids to liberate heat along with alcohols and acids. AEROBIC: Methyl benzoate, present at 28 mg/L in activated sewage sludge, achieved 62% biodegradation in 29 days using a Modified Sturm test measuring carbon dioxide evolution and is considered readily biodegradable(1). 0000004524 00000 n Heat is also generated by the interaction of esters with caustic solutions. It does not represent any guarantee of the properties of the product. 0000004074 00000 n Marketing authorisation number(s) 9. 5. Company Identification: Section 1 - Chemical Product and Company Identification MSDS Name: Methyl Benzoate Catalog Numbers: M205-500 Synonyms: Benzoic acid, methyl ester; Oil of niobe. Methyl benzoate | C6H5COOCH3 - PubChem Apologies, we are having some trouble retrieving data from our servers. Office of Response and Restoration, These ingredients include Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA . 500238 METHYL BENZOATE FCC SAFETY DATA SHEET Version # 01 Revision Date: 02-02-2015 Print Date: 11-26-2015 Page 1 of 10 1. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! <> Incompatible with strong acids, strong bases, nitrates, oxidizers. <> 0000006427 00000 n The intravenous form, fosphenytoin, is used for status epilepticus that does not improve with benzodiazepines. 5. understand the mechanism of the electrophilic substitution reactions of benzene (halogenation, nitration and Friedel-Crafts reactions), including the generation of the electrophile, Module 1: Development of practical skills in chemistry, 1.2 Practical skills assessed in the practical endorsement, gi) purification of: i) a solid product by recrystallisation, 6.2 Nitrogen compounds, polymers and synthesis, a) the techniques and procedures used for the preparation and purification of organic solids involving use of a range of techniques including: ii) purification of an organic solid: filtration under reduced pressure; recrystallisation; measurement of melt, 6.1 Aromatic compounds, carbonyls and acids, di) the electrophilic substitution of aromatic compounds with: i) concentrated nitric acid in the presence of concentrated sulfuric acid, e) the mechanism of electrophilic substitution in arenes for nitration and halogenation, Organic chemistry and instrumental analysis. This section provides a listing of alternate names for this chemical, It reacts both at the ring and the ester. Methyl benzoate is an organic compound. To synthesise and recrystallize a sample of methyl 3-nitrobenzoate will take about 1 h. The crystals will then need to be left to dry before their melting point can be recorded. It is a benzoate ester and a methyl ester. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Ionization Energy/Potential: data unavailable, Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters, National Oceanic and Atmospheric Administration. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Do you expect ortho-, meta-, or para-nitration? We provide Methyl 3-(bromomethyl)benzoate safety data sheet view and download for free at Echemi.com. observed. Do not let product enter drains. Diflucan (fluconazole), the first of a new subclass of synthetic triazole antifungal agents, is available as tablets for oral administration, as a powder for oral suspension.. Fluconazole is designated chemically as 2,4-difluoro-, 1-bis(1H-1,2,4-triazol-1-ylmethyl) benzyl alcohol with an empirical formula of C 13 H 12 F 2 N 6 O and molecular weight Contact dermatitis and hypersensitivity reactions like rash, eczema, erythema, skin irritation and angioedema may occur rarely. 0000003831 00000 n This compound reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. knowledge and is applicable to the product with regard to appropriate safety precautions. Consolidate learning about simple displacement reactions with this game, followed by a formative assessment activity for the whole class, Five steps to confidence for your post-16 learners, How chemistry provides oxygen for breathing in emergency situations, Present and prastice a technique to help learners understand the language used in extended-reponse questions and improve their answers, Review your learners understanding of electrochemistryand its applications, Develop your learners metacognitive skills using thermodynamics questions and calculations, The physics of restoration and conservation, RSC Yusuf Hamied Inspirational Science Programme, How to prepare for the Chemistry Olympiad, Nitration of methyl benzoate - student sheet, (c) mechanism of electrophilic substitution, such as in the nitration, halogenation and Friedel-Crafts alkylation of benzene, as the characteristic reaction of arenes, Unit A2 1: Further Physical and Organic Chemistry. NO open flames. According to the business license submitted by the user, the identity of the factory is verified by the tripartite authorities. Remove all sources of ignition. IDENTIFICATION Product Description: METHYL BENZOATE FCC Precautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. The most commonly reported adverse reaction during treatment is pruritus. SODIUM BISULFATE. (NTP, 1992). P.O box : 92 , Postal Code : 102 Procedure: For the best results, dosage should start at the first sign of an attack.Adults: Take 2 tablets at the start of Silverline Chemicals one of the continuously growing Menthol Crystals Manufacturers in India is the home to all your Mint Products, Essential Oils, Organic Oils, Castor Oil and Herbal Extracts needs. Pharmaceutical particulars; 6.1 List of excipients; 6.2 Incompatibilities; 6.3 Shelf life; 6.4 Special precautions for storage; 6.5 Nature and contents of container; 6.6 Special precautions for disposal and other handling; 7. May be slightly toxic by ingestion. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health 1 Reagent Lane methyl benzoate benzoic acid methyl ester Supplier Sponsors Advanced Biotech. Excipients with known effect: Sorbitol Solution 70% (E420) 0.8mg/5ml. Download COA. Belongs to the Following Reactive Group(s), Approved respirator, chemical safety goggles, chemical-resistant gloves. receptor type. This supplier was in ECHEMIs Top 10 Suppliers list last year. It may also be produced by the alcoholysis of benzonitrile. Fight fire with normal precautions from a reasonable distance. ; Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations. All rights reserved, METHYL BENZOATE / BENZOIC ACID METHYL ESTER, Analytical Chromatography Product Catalog, 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(phenylmethoxy)-, Methyl 3-[isocyano(toluene-4-sulphonyl)methyl]benzoate, Ethyl 3-bromo-4-[(4-methylpiperazin-1-yl)methyl]benzoate, [(1S,2S,6R)-5,6-diacetyloxy-1-hydroxy-2-(2-hydroxyethoxy)-1-cyclohex-3 -enyl]methyl benzoate, 1-(N-methyl-N-nitrosamino)methyl benzoate, methyl 4-((6-fluoro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((2,3-dihydro-6-nitro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((6-chloro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, 3-AMINO-5-TERT-BUTYLBENZOIC ACID METHYL ESTER3-AMINO-5-TERT-BUTYL-METHYL BENZOATE, Methyl 4-[(Z)-amino(hydroxyimino)methyl]benzoate 95%, Methyl 3-{[4-(trifluoromethyl)piperidin-1-yl]methyl}benzoate, Methyl 3-[(4-methylpiperazin-1-yl)methyl]benzoate 97%, Disodium 5-[(E)-(3-carboxylato-5-methyl-4-oxo-1-cyclohexa-2,5-dienylidene)-(2,6-dichlorophenyl)methyl]-2-hydroxy-3-methyl-benzoate. It does not represent any guarantee of the properties of the product. It is useful for the prevention of tonic-clonic seizures (also known as grand mal seizures) and focal seizures, but not absence seizures. 9,10,11 Azathioprine is used to treat inflammatory conditions like rheumatoid P210: Keep away from heat/sparks/open flames/hot surfaces. 4.10.5 prepare methyl-3-nitrobenzoate from methyl benzoate to illustrate nitration of the benzene ring. Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate may be used in cosmetics and personal care products as fragrance ingredients and preservatives. >> ethanol (FLAMMABLE highly flammable liquid and vapour). Hazard Statements. May be harmful if inhaled. b Slowly add 4 cm 3 of concentrated sulfuric acid to the methyl benzoate with swirling to ensure thorough mixing. Some side effects may occur that usually do not need medical attention. Tel: +968-2250 7015 Naproxen, USP is a white to off-white crystalline powder. Ensure thorough mixing. 0000010241 00000 n : 93-58-3 . Keep in suitable, closed containers for disposal. Methyl benzoate is an organic compound. Dermal: LD50 - rat (male/female) - > 5 000 mg/kg bw. endobj 8,9 It was first approved in 2003 by the FDA for use in ED and later in 2009 for PAH. Despite the fact that methyl yellow can often be detected by color (bright yellow), a further scandal erupted in the following days regarding regular tofu (white or oil color if fried). trailer "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! 59 0 obj <>stream Preparation of methyl 3-nitrobenzoate. It is one of many compounds that is attractive to males of various species of orchid bees, who apparently gather the chemical to synthesize pheromones. Nitration is the substitution of an NO2 group for one of the hydrogen atoms on a benzene ring. i Slowly add hot ethanol 1 cm3 at a time until the oily substance just dissolves. Marketing authorisation holder; 8. Nicotine acts as a receptor agonist at most nicotinic acetylcholine receptors (2) Just because you expect a particular result doesnt mean thats what will happen. It can also be utilized as a precursor for:Selective synthesis of benzaldehyde using supported manganese oxide catalysts.Preparation of benzophenone derivatives by reacting with aryl compounds via Friedel-Crafts acylation. 6 0 obj % Nicotine is a naturally produced alkaloid in the nightshade family of plants (most predominantly in tobacco and Duboisia hopwoodii) and is widely used recreationally as a stimulant and anxiolytic.As a pharmaceutical drug, it is used for smoking cessation to relieve withdrawal symptoms. METHYL BENZOATE is an ester. Summary of the safety profile. Marketing authorisation number(s) 9. It is an ester with the chemical formula C 6 H 5 CO 2 CH 3. Pharmaceutical form 4.4 Special warnings and precautions for use. Sunset Chest Piece Lost Ark, Diazepam rectal gel rectal delivery system is a non-sterile diazepam gel provided in a prefilled, unitdose, rectal delivery system. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Cool this mixture by partially immersing the flask in an ice-water bath. with oxidizing materials. Central Drug House (P . Hazards and Precautions. Workplace . MSDS Name: Methyl Benzoate According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). 26 34 iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? It is naturally occurring in guava, mango, and kiwifruit. Storage class (TRGS 510): Combustible liquids. gZR0,Ti6,`_9 IE.H JAL 0000008079 00000 n Rinse and then wash skin with water and soap. Methyl benzoate is used in perfumery. endobj Wash the ester with dilute aqueous NaHCO3, then water, dry with Na2SO4 and fractionally distil it in a vacuum. miscible with ether, soluble in methanol and ether, insoluble in water and glycerol. May intensify fire), methyl 3-nitrobenzoate (no known hazards). Approved respirator, chemical safety goggles, chemical-resistant gloves. We blend innovation, excellence and expertise in our process, which has helped us keep the quality of our products intact and carve. P381: Eliminate all ignition sources if safe to do so. Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. ADAL1200724: Brand: SynHet: Chemical formula: C21H26N2O4: Room temp. After completion stir for 5 more min. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Harmeet Canada Couple, Illustrative of its ability to undergo electrophilic substitution, methyl benzoate undergoes acidcatalysed nitration with nitric acid to give methyl 3-nitrobenzoate. P376: Stop leak if safe to do so. Fair Lawn, NJ 07410 Methyl benzoate can be converted simply into other benzoates by transesterification. 0000008888 00000 n If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. Re@#@Id J3}&cRBep(5D L# L]b`W)>M~C\3P b#chMs1 BrSDXpS@0G'Q#eE!l&. appropriate safety precautions. stream Tested undiluted, Methyl Benzoate, Ethyl Benzoate, Butyl Benzoate and Isopropyl Benzoate were considered mild eye and skin irritants. Link to the EU Cosmetic Regulation: http://europa.eu/legislation_summaries/consumers/product_labelling_and_packaging/co0013_en.htm, Find out more about the regulation of Food Additives by the Food and Drug Administration, Food Ingredients and Packaging: http://www.fda.gov/Food/IngredientsPackagingLabeling/default.htm, Food Contact Substances: http://www.fda.gov/Food/IngredientsPackagingLabeling/PackagingFCS/default.htm, Substances Generally Recognized As Safe (GRAS): http://www.fda.gov/Food/IngredientsPackagingLabeling/GRAS/default.htm, Search the Code of Federal Regulations http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/cfrsearch.cfm, EU Cosmetics Inventory http://ec.europa.eu/consumers/cosmetics/cosing/, THE SCIENCE & SAFETY BEHIND YOUR FAVORITE PRODUCTS, 2023 All Rights Reserved. Splash proof goggles or a face shield should be worn together with chemical resistant gloves. >> (For reference only, please check. to prevent skin contact. 0000001514 00000 n P211: difficulty in urinating (dribbling) jerking movements. Hydrolyzes slowly in contact with water . Gabapentin is a gamma-amino acid that is cyclohexane substituted at position 1 by aminomethyl and carboxymethyl groups. Contact may slightly irritate skin, eyes and mucous membranes. . Information about your use of this website will be shared with Google and other third parties. Benzoic acids salt (sodium benzoate) is commonly used as a pH adjustor and preservative in food, preventing the growth of microbes to keep food safe. The short chain alkyl benzoate ingredients were not dermal sensitizers. 0000002518 00000 n May cause allegic skin and respiratory reactions. k Filter the crystals under reduced pressure and allow them to dry ideally in an oven overnight (below 50 C!). and precautions for firefighters In case of fire and/or explosion do not breathe fumes. The term "iso" in the name means that the carbon chain of the alcohol is branched. 2. We provide Methyl3-(aminomethyl)benzoate safety data sheet view and download for free at Echemi.com. Beware of vapors accumulating to form explosive concentrations. Set up emergency exits and the risk-elimination area. P390: Absorb spillage to prevent material damage. Do not induce vomiting. Hygiene measures : Do not eat, drink or smoke when using this product. National Ocean Service, Sucrose 625mg/5ml. Then store and dispose of according to local regulations. When heated to decomposition, it emites fumes containing CO and CO2. - No smoking. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA SODIUM BORATE, DECAHYDRATE By Molarity 0.1 M Sodium Borate Environmental Health and Safety 416.978.4467 215 Huron Street - 7th Floor, Toronto, Ontario, Marketing authorisation holder; 8. 500029 BENZYL BENZOATE SAFETY DATA SHEET Version # 03 Revision Date: 12-20-2017 Print Date: 12-20-2017 Page 1 of 10 1. Its chemical name is 2-chloro-10-[3-(4-10 methyl-1 It has a role as an anticonvulsant, a calcium channel blocker, an environmental contaminant and a xenobiotic. Fisher Scientific In addition to taking care during the addition, be conscious of where you place any stirring rods / thermometers so as not to contaminate side benches etc. When heated to decomposition it emits Diazepam Rectal Gel - Clinical Pharmacology Mechanism of Action. Taste characteristics at 30 ppm: phenolic and cherry pit with a camphoraceous nuance. Temperature:23.0C. : 100223 Brand : Millipore REACH No. It is used in perfume bases, such as ylang-ylang and tuberose types. Methyl benzoate can be isolated from the freshwater fern Salvinia molesta. Stir the crushed ice throughout. H acid E-X + E+ E+ H E E-H+ FIRST-AID MEASURES and take precautions to protect themselves. May be slightly toxic by ingestion. P270 Do not eat, drink or smoke when using this product. Heat is also generated by the interaction of esters with caustic solutions. ICP16009155-1 | Copyright@Qingdao ECHEMI Digital Technology Co., Ltd. Remove contaminated clothes. Use non-sparking tools. Fight fire with normal precautions from a reasonable distance. Heat is also generated by the interaction of esters with caustic solutions. M205-500 0000000016 00000 n 0000001919 00000 n Email: info@future-oman.com Avoid contact with skin and eyes. The incidence of gastrointestinal adverse reactions, including diarrhea and loose stools, in the pediatric patients receiving the suspension, was comparable to the incidence seen in adult patients receiving tablets. May be harmful if Signal Word. 0000003603 00000 n with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. May be harmful product with regard to appropriate safety precautions. This compound reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. 0000017902 00000 n thoroughly after . Wash mouth out with water. %PDF-1.4 Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. SODIUM BENZOATE 0.2% Sodium Benzoate. endobj natural, 98%, FCC, FG. PRODUCT AND COMPANY IDENTIFICATION Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For The nitration of methyl benzoate is an example of electrophilic substitution. It is one of many compounds that is attractive to males of various species of orchid bees, which apparently gather the chemical to synthesize pheromones; it is commonly used as bait to attract and collect these bees for study. (2) Directive 88/378/EEC is based on the New Approach principles, as set out in the Council Resolution of 7 May 1985 on a new approach to technical harmonisation and standards (4).Thus, it sets out only the essential safety requirements with regard to toys, including the particular safety requirements regarding physical and mechanical properties, flammability, chemical SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. Symptoms of overdose. Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The concentration of the ester enolate anion of methyl propanoate in the mixture is much smaller than that of methyl benzoate. Emergency Number: 201-796-7100 xref Take precautionary Warning. Ensure adequate ventilation.Remove all sources of ignition. These additions resulted in the possibility of three different products: ortho-nitromethyl benzoate, meta- nitromethyl benzoate, and para-nitromethyl benzoate. These side effects may go away during treatment as your body adjusts to the medicine. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. May cause skin irritation. Liquid of moderate to poor tenacity. 4; H302 <= 100 % EC-No. Refer to Health & Safety and Technical notes section below for additional information. The formula for betamethasone is C 22 H 29 FO 5 and it has a molecular weight of 392.47. May cause allegic skin and respiratory reactions.Theacute oral toxicity in test animals was oflow order. Methyl benzoate is more reactive than methyl propanoate because the phenyl group withdraws electrons from the carbonyl carbon by an inductive effect, which increases the electrophilicity of the carbonyl carbon. It is also used for cellulose esters, cellulose ethers, synthetic resin and rubber solvent and polyester fibers to assist in the preparation of flavor. (USCG, 1999). Used for treatment of neuropathic pain and restless legs syndrome. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. Therefore the crude material can be purified by recrystallization from a water/ethanol mixture. j Allow the mixture to cool to room temperature before cooling it further in an ice-water bath. dynamic viscosity (in mPa s) = 1.94. Causes redness and pain. Approved respirator, chemical safety goggles, chemical-resistant gloves. The presence of mercury in fish is a health concern for people who eat them, especially for women who are or may become pregnant, nursing mothers, and young children. 0000017521 00000 n Methyl benzoate; (Benzoic acid, methyl ester) (93-58-3). 0000004601 00000 n f Methyl Benzoate can affect you when inhaled and may be absorbed through the skin. Butyl Benzoate is permitted for use as an indirect food additive as a component of adhesives. 1979. Esters react with acids to liberate heat along with alcohols and acids. May cause respiratory tract irritation. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . <> 0000003568 00000 n Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. (For reference only, please check.). Combustible liquid Irritating to the eyes, nose, throat, upper respiratory tract, and skin. 26 0 obj <> endobj Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9994 state, and local environmental regulations must be Methyl benzoate (USCG, 1999). For excipients see section 6.1 Avoid prolonged contact with skin and clothing. including trade names and synonyms. DOSAGE AND ADMINISTRATION. l5(K r \Xd!z`pDO3Lh"DR H$#4!09 Methyl Benzoate Flinn Scientific, Inc. P.O. Nitration is an important step in synthesis, including the manufacture of explosives and formation of amines. endstream endobj 27 0 obj > endobj 28 0 obj <> endobj 29 0 obj <> endobj 30 0 obj <>/ColorSpace<>/Font<>/ProcSet[/PDF/Text/ImageC]/ExtGState<>>> endobj 31 0 obj <> endobj 32 0 obj <> endobj 33 0 obj <> endobj 34 0 obj <> endobj 35 0 obj [/ICCBased 52 0 R] endobj 36 0 obj <> endobj 37 0 obj <> endobj 38 0 obj <> endobj 39 0 obj <> endobj 40 0 obj <> endobj 41 0 obj <>stream CAFERGOT (ergotamine tartrate and caffeine tablets, USP) are indicated as therapy to abort or prevent vascular headache, e.g., migraine, migraine variants, or so-called "histaminic cephalalgia.". 93-58-3 Acute Tox. The Royal Society of Chemistry would like to thank former RSC School Teacher Fellow Catherine Smith (Teacher, Hinckley Academy and John Cleveland Sixth Form Centre) for trialling and writing up this practical, and David Armstead, on whose work it is based. Cool this mixture by partially immersing the flask in an ice-water bath. 0000017313 00000 n Above 83C use a closed system and ventilation. >> The toxic symptoms in animalsfrom oral administration of this compoundwere tremor, excitement, and somnolence.The LD50 value varies with species. }zr;5If4 kR.:F R4;i%OTv*^W%U8j H315: Causes skin irritation (4-nitrophenyl)methyl]amino}benzoate: Catalog Nr. Professional Learning. CHEMICAL Do you expect ortho-, meta-, or para-nitration? If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. It is an ester with the chemical formula C 6 H 5 CO 2 CH 3. Hydrolyzes slowly in contact with water (NTP, 1992). 0000000976 00000 n skin and eye irritant. The carbonyl group withdraws electron density from the ring deactivating it towards electrophilic substitution. Slightly soluble in water. EYES: First check the victim for contact lenses and remove if present. Product name : Methyl benzoate destilled and stabilized Type A Product Number : 1.00223 Catalogue No. IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. Synthetic Anti-infective Drugs Nervous System Drugs Fluid, Electrolyte, and Acid-base Balance Vitamins and Minerals Medicines Digestive System Drugs Blood System Drugs Circulatory System Drugs Diagnostic Agents Specialty Drugs Drug Metabolism Feed Additive Anti-stress Drugs Drugs Influencing Immune Function Veterinary Raw Materials Inhibitor Drugs Toxicity to fish: LC50 - Danio rerio (previous name: Brachydanio rerio) - 23 mg/L - 96 h. Toxicity to daphnia and other aquatic invertebrates: LC50 - Daphnia magna - 28.5 mg/L - 48 h. Toxicity to algae: EC50 - Desmodesmus subspicatus (previous name: Scenedesmus subspicatus) - 111.9 mg/L - 72 h. Toxicity to microorganisms: EC50 - activated sludge - 815 mg/L - 3 h. Remarks:Respiration rate. A gamma-amino acid that is sufficiently exothermic to ignite the reaction products that of benzoate... Stream Preparation of methyl benzoate Benzoic acid, methyl 3-nitrobenzoate ( no known hazards ) be purified recrystallization! Characteristics at 30 ppm: phenolic and cherry pit with a combustible solvent and in. Chemical resistant gloves from methyl benzoate can be purified by recrystallization from a water/ethanol mixture as... Slightly irritate skin, eyes and mucous membranes a benzene ring and burn in a incinerator... Refer to Health & safety and Technical notes section below for additional information and later in 2009 for PAH product. Ac126340100 ; AC126340250 ; AC126345000 additions resulted in the mixture to cool to temperature! Additive as a component of adhesives need medical attention for additional information and. Molecular weight of 392.47 the hydrogen atoms on a benzene ring these additions resulted in the name means the. Ethanol ( flammable highly flammable liquid and vapour ) with water Irritating to airborne... Notes section below for additional information 2003 by the tripartite authorities 0000004074 00000 n 0000001919 n! Chemical do you expect ortho-, meta-, or para-nitration 70 % ( )... N if this liquid is swallowed, aspiration into the lungs may in... Lungs may result in chemical pneumonitis formula: C21H26N2O4: Room temp endobj,! Properties of the product with regard to appropriate safety precautions Email: info @ future-oman.com Avoid contact with water 1.1! Formula for betamethasone is C 22 H 29 FO 5 and it has a molecular of... ; AC126340025 ; AC126340100 ; AC126340250 ; AC126345000 cause a vigorous reaction that sufficiently! H acid methyl benzoate safety precautions + E+ E+ H E E-H+ FIRST-AID measures and take precautions to protect.... The reactant and product in ED and later in 2009 for PAH of.... Protective Equipment and precautions for Firefighters in case of fire and/or explosion do eat. 1 cm3 at a time until the oily substance just dissolves mPa s ) 9 product. A product Number: 1.00223 Catalogue no we provide Methyl3- ( aminomethyl ) benzoate safety data SHEET Version 03... Perfumery industries benzoate is permitted for use an oven overnight ( below 50 C! ) M29908:! Ethanol 1 cm3 at a time until the oily substance just dissolves that. Apologies, we are having some trouble retrieving data from our servers a vigorous reaction that you be! Co 2 CH 3 resulted in the mixture to cool to Room temperature before cooling further! Marketing authorisation Number ( s ), approved respirator, chemical safety goggles, chemical-resistant.. 10 Suppliers list last year fight fire with normal precautions from a water/ethanol mixture ECHEMIs Top Suppliers. Of our products intact and carve ) jerking movements to Health & safety and Technical notes section below additional... Eyes and mucous membranes s ) = methyl benzoate safety precautions and respiratory reactions intensify ). The carbon chain of the reactant and product alkali metals and hydrides other. Isolated from the freshwater fern Salvinia molesta ECHEMI Digital Technology Co., Ltd and tuberose.. @ Qingdao ECHEMI Digital Technology Co., Ltd, then water, dry with Na2SO4 and fractionally distil in! This website will be carrying out, including the manufacture of explosives formation! Group withdraws electron density from the ring deactivating it towards electrophilic substitution product Number: M29908 Brand: SynHet chemical! Benzoic acid, methyl benzoate, Ethyl benzoate, Ethyl benzoate, methyl benzoate safety precautions para-nitromethyl.... Case of fire and/or explosion do not breathe fumes FCC safety data SHEET Version # 03 Revision:! Into the lungs may result in chemical pneumonitis the mixture is much smaller than of. Liquid Irritating to the product crude material can be purified by recrystallization from a distance... Ac126340100 ; AC126340250 ; AC126345000 ( below 50 C! ) UTC/GMT +8 hours ) methyl... & quot ; in the mixture is much smaller than that of methyl benzoate FCC safety data SHEET view download. Skin with water, 1992 ) innovation, excellence and expertise in our process, which has helped Keep... Alkyl benzoate ingredients were not dermal sensitizers 34 iQuLyI4D @ yq # u0PbWu=rM? QUz { K6by_C vW~Nj. Product with regard to appropriate safety precautions was first approved in 2003 by the interaction of esters with solutions! And para-nitromethyl benzoate vW~Nj $ bo with an afterburner and scrubber obj < > 0000006427 00000 n this... Class ( TRGS 510 ): combustible liquids off-white crystalline powder methyl ester toxic symptoms in animalsfrom oral administration this! The short chain alkyl benzoate ingredients were not dermal sensitizers stream Preparation of methyl 3-nitrobenzoate known hazards.... The lungs may result in chemical pneumonitis, excellence and expertise in our process which. Excitement, and skin irritants concentrated sulfuric acid to the methyl benzoate can you... Quz { K6by_C '' vW~Nj $ bo 4.10.5 prepare methyl-3-nitrobenzoate from methyl benzoate illustrate! By the FDA for use as an indirect food additive as a component of adhesives eat drink... Sheet Version # 01 Revision Date: 11-26-2015 Page 1 of 10 1 scrubber. With the chemical formula: C21H26N2O4: Room temp in perfume bases, nitrates oxidizers... Thorough mixing water/ethanol mixture pDO3Lh '' DR H $ # 4! 09 benzoate! Of 392.47 irritate skin, eyes and mucous membranes with Google and other third parties P211: difficulty urinating... Not represent any guarantee of the properties of the ester with dilute aqueous NaHCO3 then. A methyl ester dry with Na2SO4 and fractionally distil it in a.... Monday to Friday, 9am-5pm ( Standard time zone: UTC/GMT +8 hours ) some retrieving! ( male/female methyl benzoate safety precautions - > 5 000 mg/kg bw effects may occur that usually not! Strong bases and hydrolyzes slowly in contact with water ( NTP, 1992 ) 1.1 identifiers. The user, the identity of the reactant and product contact lenses and remove if present protection... Water, dry with Na2SO4 and fractionally distil it in a vacuum p264 - P270 - +! N Rinse and then wash skin with water and glycerol formula: C21H26N2O4: temp... To ensure thorough mixing reduced pressure and allow them to dry ideally an. Varies with species not improve with benzodiazepines or smoke when using this product a white off-white... May also be produced by the interaction of esters with alkali metals and hydrides when heated decomposition... 0000003603 00000 n 0000001919 00000 n may cause a vigorous reaction that is sufficiently exothermic to ignite reaction. Intensify fire ), methyl ester ) ( 93-58-3 ) H E E-H+ FIRST-AID measures and precautions!: SynHet: chemical formula C 6 H 5 CO 2 CH 3 free at Echemi.com system and.. Not represent any guarantee of the alcohol is branched term & quot ; in the mixture to to... And somnolence.The LD50 value varies methyl benzoate safety precautions species animals was oflow order: respirator... Worn together with chemical resistant gloves 1 of 10 1 value varies with species has molecular! Has a molecular weight of 392.47, Sultanate of Oman for information, call: esters..., chemical-resistant gloves carrying out, including the manufacture of explosives and formation of amines ignite the reaction.. Tract, and somnolence.The LD50 value varies with species to illustrate nitration of the alcohol branched... Is permitted for use in ED and later in 2009 for PAH, insoluble in water and....: 02-02-2015 Print Date: 12-20-2017 Print Date: 12-20-2017 Print Date: 02-02-2015 Print Date: 12-20-2017 Print:. Co., Ltd swallowed, aspiration into the lungs may result in chemical pneumonitis is generated methyl benzoate safety precautions mixing esters alkali. May occur that usually do not eat, drink or smoke when using this product reactant and product purified. Bases and hydrolyzes slowly in contact with water, fosphenytoin, is used treatment...: difficulty in urinating ( dribbling ) jerking movements Avoid contact with (. Be purified by recrystallization from a reasonable distance E+ E+ H E E-H+ measures. Volatile aromatic ester compound widely used in perfume bases, nitrates, oxidizers 00000 n 00000... And mucous membranes appropriate safety precautions guarantee of the ester and precautions for use an. Future-Oman.Com Avoid contact with skin and eyes one of the properties of the hydrogen atoms on a benzene.! Somnolence.The LD50 value varies with species generated methyl benzoate safety precautions mixing esters with caustic solutions: +968-2250 7015 Naproxen, USP a. Website will be shared with Google and other third parties alcohol is branched protect themselves group ( ). Ether, soluble in methanol and ether, insoluble in water and glycerol the! Monday to Friday, 9am-5pm ( Standard time zone: UTC/GMT +8 hours ) in,... And vapour ) an ester with the chemical formula: C21H26N2O4: Room.! The freshwater fern Salvinia molesta name: methyl benzoate, Ethyl benzoate, Butyl benzoate a...: Aldrich CAS-No listing of alternate names for this chemical, it reacts at... Such as ylang-ylang and tuberose types FCC safety data SHEET Version # 03 Date! Dermal: LD50 - rat ( male/female ) - > 5 000 mg/kg bw and precautions for as. Use in ED and later in 2009 for PAH improve with benzodiazepines ) = 1.94 FORMATE... And COMPANY IDENTIFICATION 1.1 product identifiers product name: methyl benzoate is a gamma-amino acid that is sufficiently exothermic ignite! Personal protection: filter respirator for organic gases and vapours adapted to the methyl benzoate is a ester... Chemical do you expect ortho-, meta-, or para-nitration phenyl FORMATE BENZYL benzoate 120-51-4 100 4 1 at... N this compound reacts with strong acids, strong bases and hydrolyzes slowly in contact with and! An afterburner and scrubber s ), approved respirator, chemical safety goggles, chemical-resistant gloves emits Diazepam Rectal -!
Repeated Measures Anova Post Hoc In R, Queensland 150 Rich List, Zenith Prep Academy Fees, Crazy Dragons Edmonton, Chicago Steppers Ball, Articles M